Pokémon Diamond and Pearl/Route 215
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As soon as you enter, it starts to rain. This is a rainy area.
TM66 Payback can be obtained from one of the Black Belts.
Keep following the Galactic Grunt from Pastoria City. He will lead you to Cynthia.
You can also find a Fist Plate here, a Hold item that boosts the power of Fighting-type moves.