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Dual-slot mode, is a way that you can use to obtain Pokémon that are out of the Sinnoh Dex, by putting the GBA Pokemon games in the DS slot.

With any of the five Game Boy Advance games inserted while playing either Diamond or Pearl, you will find wild Pokémon not otherwise available in Sinnoh (except migration at Pal Park).

List of Pokémon available by inserting older games chips

Pokémon Ruby
Pokémon Location
Seedot Routes 203, 204 and 210, Eterna Forest
Nuzleaf Routes 210 and 229
Mawile Iron Island
Zangoose Routes 208 and 210
Solrock Lake Verity, Lake Acuity, Lake Valor, Mt. Coronet, Sendoff Spring, Turnback Cave
Pokémon Sapphire
Pokémon Location
Lotad Routes 203, 204, 205, and 212 (south)
Lombre Routes 212 (south) and 229
Sableye Iron Island
Seviper Routes 208 and 210
Lunatone Lake Verity, Lake Acuity, Lake Valor, Mt. Coronet, Sendoff Spring, Turnback Cave
Pokémon Emerald
Pokémon Location
Pineco Eterna Forest, Routes 203, 204, and 229
Gligar Stark Mountain, Routes 206, 207, 214, 215, and 227
Shuckle Route 224
Teddiursa Route 211, Lake Acuity
Ursaring Routes 216 and 217, Lake Acuity
Pokémon FireRed
Pokémon Location
Caterpie Route 204
Metapod Eterna Forest
Ekans Route 212 (south)
Arbok Great Marsh
Growlithe Routes 201 and 202
Elekid Routes 204 and 205, Valley Windworks
Pokémon LeafGreen
Pokémon Location
Weedle Route 204
Kakuna Eterna Forest
Sandshrew Wayward Cave
Sandslash Route 228
Vulpix Routes 209 and 214
Magby Route 227, Stark Mountain
Any Generation III game
Pokémon Location
Haunter Old Chateau
Gengar Old Chateau