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There are all sorts of accessories available in the game, and each bestows a different combat advantage. You'll want to get a hold of a wide selection so you can pick and choose between battle strategies.

Name Description Where to find/purchase
Fire Ring Nullifies [Fire] Attacks Basement of Costa del Sol house
Headband Protects against [Sleep] Accessory shop in Junon, and in Gongaga for 3000 gil
Peace Ring Protects against [Berserk/Fury/Sadness] Receive after winning 2nd Fort Condor battle
Power Wrist "Strength" +10
Protect Vest "Vitality" +10 Receive after defeating Rufus in Shinra Bldg
Silver Glasses Protects against [Darkness] Accessory shop in Junon, and Gongaga for 3000 gil
Star Pendant Protects against [Poison] Receive for trading in A Coupon on the 63rd floor of the Shinra Bldg; Receive for defeating Motor Ball boss
Talisman "Spirit" +10 Receive after defeating Sample: HO512 on the 67th floor of the Shinra Bldg
Tough Ring "Vitality"&"Spirit" +50
White Cape Protects against [Frog/Small] Receive after defeating Jenova-BIRTH, Ho-Chu; and Accessory shop in Gongaga and Mideel for 5000 gil