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There are all sorts of accessories available in the game, and each bestows a different combat advantage. You'll want to get a hold of a wide selection so you can pick and choose between battle strategies.

Name Description Where to find/purchase
Choco Feather Dexterity +10 Wutai Shop for 10000 gil
Earring Magic + 10 Rocket Town shop
Fairy Ring Protects against [Poison/Darkness] Chest in Cave of the Gi
Fire Ring Nullifies [Fire] Attacks Basement of Costa del Sol house
Fury Ring Automatically puts you in [Berserk] Shop in Gongaga for 5000
Headband Protects against [Sleep] Accessory shop in Junon, and in Gongaga for 3000 gil
HypnoCrown Increases Manipulation rate Treasure chest before entering Icicle Inn
Jem Ring Protects against [Paralyze/Petrify/Slow-numb] Receive after defeating Materia Keeper in Mt. Nibel
Peace Ring Protects against [Berserk/Fury/Sadness] Receive after winning 2nd Fort Condor battle
Power Wrist "Strength" +10
Protect Vest "Vitality" +10 Receive after defeating Rufus in Shinra Bldg
Ribbon Protects against all abnormal status Treasure chest in Temple of the Ancients and Gaea Cliffs, Morph from Master Tonberry
Silver Glasses Protects against [Darkness] Accessory shop in Junon, and Gongaga for 3000 gil
Star Pendant Protects against [Poison] Receive for trading in A Coupon on the 63rd floor of the Shinra Bldg; Receive for defeating Motor Ball boss
Talisman "Spirit" +10 Receive after defeating Sample: HO512 on the 67th floor of the Shinra Bldg
Tough Ring "Vitality"&"Spirit" +50 Steal from Reno (3/Gelnika and 4/Midgar)
Water Ring Drains Water attacks Found in Coral Valley, and steal from Acrophies and Serpents
White Cape Protects against [Frog/Small] Receive after defeating Jenova-BIRTH, Ho-Chu; and Accessory shop in Gongaga and Mideel for 5000 gil