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Mt. Coronet is a long range of mountains that divide the Sinnoh region in half. Most of it is a deep cave, though there are several above-ground areas. The name is a reference to the word corona. This time, Team Galactic has headed up here to accomplish their goal of creating a new world. Of course, you have to stop them.

The mountain's peak is the Spear Pillar, where Dialga or Palkia are awakened, and where the Hall of Origin is reached.

Before coming here, make sure your Pokémon are fully healed. Stock up on Moomoo Milks, Lemonades, and Ice Heals as the journey is going to be long and you will encounter another Blizzard which makes it hail and any non ice Pokémon will be hurt by it in battles.

Also you will be fighting and catching the game's box cover Legendary Pokémon, Dialga in Diamond and Palkia in Pearl, so bring a Pokemon that knows a sleep inducing move. In Diamond bring at least 40 Ultra Balls and in Pearl bring 40 Net Balls which can be bought in Hearthome City, Etetna City and Solaceon Town. If you are catching the Legendary Pokémon at night then you can bring 40 Dusk Balls which can bought in Pastoria City and Snowpoint City

Also the wild Pokémon in the upper floors are all above level 40 so make sure your team can beat them or bring Repels (not recommended since you need the xp)

When you are ready fly to Hearthome City and exit to the east and go onto Route 208

Route 208[edit]

Near the entrance to Mt. Coronet is a climbable wall with Hiker Alexander and a hidden Iron. When done head into Mt. Coronet.

Trainers[edit]

Diamond and Pearl
Trainer Pokemon
Hiker Alexander
Hiker Alexander
Reward: Pokebuck.png1120
  • Golbat Golbat Lv. 35
  • Graveler Graveler Lv. 35
  • Onix Onix Lv. 35

Items[edit]

  • Iron (hidden) - in wall next to Hiker Alexander

1F 1[edit]

1F 1
Diamond & PearlPlatinum
1F 1
1F 1

When you come in here you want to head to the northwest corner and surf east over the water. Continue east to the climbable wall and be careful to not jump over the ledge. Head north then up the stairs to reach 2F.

Pokémon found[edit]

Here is your first chance to catch a Cleffa (DP), Clefairy (Platinum), Nosepass (Platinum), Meditite, and Chingling

Diamond and Pearl
Pokémon Level Morn. Day Night
Zubat Zubat 14,15 10% 20% 20%
Machop Machop 15,16 25% 25% 25%
Geodude Geodude 14,15 20% 30% 30%
Cleffa Cleffa 14 25% 5% 5%
Nosepass Nosepass - - - -
Meditite Meditite 15 10% 10% 10%
Chingling Chingling 15 10% 10% 10%
Bronzor Bronzor - - - -
Surfing
Zubat Zubat 20-40 90% 90% 90%
Golbat Golbat 20-40 10% 10% 10%
Platinum
Pokémon Level Morn. Day Night
Clefairy Clefairy 17 10% - 10%
Zubat Zubat 18,19 5% 5% 15%
Machop Machop 20 10% 10% 10%
Geodude Geodude 17,19 20% 30% 20%
Nosepass Nosepass 18 5% 5% 5%
Meditite Meditite 18,20 20% 20% 10%
Chingling Chingling 17,19 10% 10% 10%
Bronzor Bronzor 18 20% 20% 20%
Surfing
Zubat Zubat 20-30 90% 90% 90%
Golbat Golbat 20-40 10% 10% 10%
Diamond and Pearl
Pokémon Level Old Rod Good Rod Super Rod
Magikarp Magikarp 3-10 100% - -
Magikarp Magikarp 10-25 - 55% -
Barboach Barboach 10-25 - 45% -
Gyarados Gyarados 30-55 - - 55%
Whiscash Whiscash 20-50 - - 45%
Platinum
Pokémon Level Old Rod Good Rod Super Rod
Magikarp Magikarp 3-15 100% - -
Magikarp Magikarp 10-25 - 55% -
Barboach Barboach 15-35 - 45% -
Gyarados Gyarados 20-50 - - 55%
Whiscash Whiscash 30-55 - - 45%

Items[edit]

  • Ether (hidden) - northern rock in center

2F[edit]

2F
Diamond & PearlPlatinum
2F
2F

Follow the path north then west and take the first stairs to your right. On this ledge is a Max Potion and to the west on a rock is a hidden Ether. Go back to the pathband continue west then south. All the way south next to the wall is an Escape Rope. On your way to the Escape Rope you past some stairs so go back to them and go up then go southwest to an exit. You are now back on Route 207 but higher on the mountain. Go south and go down the climbable wall. At the end of this path is an Iron. Go back inside Mt. Coronet and head back to the stairs and this time go north of them and over the bridge. Go down the stairs to the left and up the stairs to the right. Follow this path alle the way to the end and you will find TM80 Rock Slide. Go back to the stairs and go north up the next stairs. Northwest of the stairs is a Revive. Continue north and follow the path to go through the exit to the northwest section of 2F. Follow the path and go up the stairs to 3F then go forward down the next stairs to the northeast section of 2F. Go south and go up the stairs and on the rock is a hidden Max Revive. Go back up the stairs to 3F.

Pokémon found[edit]

Diamond and Pearl
Pokémon Level Rate
Clefairy Clefairy 36-38 15%
Golbat Golbat 37 10%
Machoke Machoke 37 10%
Graveler Graveler 36 20%
Medicham Medicham 37 10%
Chingling Chingling 37,38 10%
Bronzor Bronzor 36 5%
Bronzong Bronzong 37 20%

Items[edit]

  • Max Potion - on ledge north of stairs to 1F
  • Ether (hidden) - on a rock west of the Max Potion
  • Escape Rope - southwest of Max Potion
  • TM80 Rock Slide - north of Route 207 exit
  • Revive - southwest of exit to northwestern section of 2F
  • Max Revive (hidden) - on a rock in isolated northeast section

3F[edit]

3F
Diamond & PearlPlatinum
3F
3F

Once you are back on 3F head north and up the stairs. You will find a Galactic Grunt to fight. Continue west and on the rock in the corner is a hidden Super Repel. Continue south and there is another Galactic Grunt to battle. Continue south and go through the exit to go out to the summit.

Trainers[edit]

Diamond and Pearl
Trainer Pokemon
Galactic Grunt
Galactic Grunt
Reward: Pokebuck.png1600
  • Beautifly Beautifly Lv. 40
Galactic Grunt
Galactic Grunt
Reward: Pokebuck.png1560
  • Bronzor Bronzor Lv. 39

Pokémon found[edit]

Diamond and Pearl
Pokémon Level Rate
Clefairy Clefairy 36-38 15%
Golbat Golbat 37 10%
Machoke Machoke 37 10%
Graveler Graveler 36 20%
Medicham Medicham 37 10%
Chingling Chingling 37,38 10%
Bronzor Bronzor 36 5%
Bronzong Bronzong 37 20%

Items[edit]

  • Super Repel (hidden) - on a rock in the northwest corner

First visit to the Summit[edit]

Summit
Diamond & PearlPlatinum
Summit
Summit

The summit is a big area and it has alot of entrances to different floors of Mt. Coronet. Some of the entrances are dead ends but have items in them and some of them progress you through the mountain to reach the top of it. The guide will take you through every entrance to obtain all the items and fight every trainer.

Go east through the grass and in a bare patch of the grass is a Full Heal. Continue north and climb both walls. On this cliff is rock that has a hidden Nugget on it. Climb back down one wall only. To the east is one entrance to 4F 1 that is a dead end for now but it has some items in it which will be covered in the 4F 1 section. For now go west and take your first left (before the stairs). Follow this path and you will find a breakable rock and behind it there is a rock with a hidden Max Potion on it. Go up the stairs next to you and go north through the western entrance to 4F 1

Pokémon found[edit]

Diamond and Pearl
Pokémon Level Morn. Day Night
Clefairy Clefairy 38,39 5% 5% 5%
Golbat Golbat 39 - - 10%
Machoke Machoke 39,40 20% 20% 10%
Noctowl Noctowl 39 - - 10%
Medicham Medicham 39,40 20% 20% 10%
Chingling Chingling 39,40 10% 10% 10%
Bronzong Bronzong 39,40 5% 5% 5%
Snover Snover 38 20% 20% 20%
Abomasnow Abomasnow 40 20% 20% 20%

Items[edit]

  • Full Heal (hidden) in a bare patch of the grass east of the entrance to 3F
  • Nugget (hidden) - on a rock on cliff north of eastern entrance to 4F 1
  • Max Potion (hidden) - on a rock south of western entrance to 4F 1

4F 1[edit]

4F 1
4F 1

From the eastern entrance go up the stairs and on the rock is a hidden Ultra Ball. Go back the stairs and on a rock behind the first breakable rock is a hidden PP Up. Continue west and in the wall behind the next breakable rock is a hidden TinyMushroom.

The western entrance is where you can progress through the mountain to reach Spear Pillar. When you enter go north and climb the wall and continue north to battle a Galactic Grunt. Next to the Grunt is a rock behind a breakable rock and it has a hidden Revive on it. Follow the path east and on the second rock between the two Grunts is a hidden Ether. Continue east to battle the next Galactic Grunt. Go down the stairs near the Grunt and on the rock next to the stairs is a hidden Escape Rope. Continue east through the exit to get back to the Summit

Trainers[edit]

Diamond and Pearl
Trainer Pokemon
Galactic Grunt
Galactic Grunt
Reward: Pokebuck.png1400
  • Beautifly Beautifly Lv. 35
  • Golbat Golbat Lv. 38
  • Beautifly Beautifly Lv. 35
Galactic Grunt
Galactic Grunt
Reward: Pokebuck.png1520
  • Stunky Stunky Lv. 38
  • Golbat Golbat Lv. 38

Pokémon found[edit]

Note:Return here later with the Super Rod to obtain more powerful Pokémon.

Diamond and Pearl
Pokémon Level Rate
Clefairy Clefairy 38-40 15%
Golbat Golbat 39 10%
Machoke Machoke 39 10%
Graveler Graveler 38 20%
Medicham Medicham 39 10%
Chingling Chingling 39,40 10%
Bronzong Bronzong 38-40 25%
Surfing
Zubat Zubat 20-40 90%
Golbat Golbat 20-40 10%
Diamond and Pearl
Pokémon Level Old Rod Good Rod Super Rod
Magikarp Magikarp 3-10 100% - -
Magikarp Magikarp 10-25 - 55% -
Barboach Barboach 10-25 - 45% -
Gyarados Gyarados 30-55 - - 55%
Dratini Dratini 15-25 - - 40%
Dragonair Dragonair 15-40 - - 5%

Items[edit]

  • Ultra Ball (hidden) - on a rock north of eastern entrance
  • PP Up (hidden) - on a rock behind first breakable rock west of eastern entrance
  • TinyMushroom (hidden) - on the wall behind second breakable rock next to waterfall
  • Revive (hidden) - on a rock behind a breakable rock next to the first Galactic Grunt
  • Ether (hidden) - on second rock between the two Galactic Grunts
  • Escape Rope (hidden) - on a rock south of the second Galactic Grunt

Back on the Summit[edit]

Welcome back to the snowy Summit. When you first arrive here go to the southermost breakable rock and in the wall next to is a hidden Stardust. Follow the path north and through the grass and at the end on a rock is a hidden Rare Candy. Go up the climbable wall and go south to enter the entrance to 1F 2

Pokémon found[edit]

The Pokémon don't change in the different sections of the summit so refer to table in the first visit section

Items[edit]

  • Stardust (hidden) - in wall behind a breakable rock south of entrance to 4F 1
  • Rare Candy (hidden) - on a rock north of entrance to 1F 2

1F 2[edit]

1F 2
Diamond & PearlPlatinum
1F 2
1F 2

This floor is actually the way to exit Mt. Coronet which is blocked by a Galactic Grunt who claims to be lost. You are coming here now to fight the Galactic Grunts before they vanish when you complete the other events later on. Once you are done with all the events in Mt. Coronet the exit wont be blocked and it will take you to the northern section of 1F 1 and will have exits to the east and west of Route 211. You might as well collect the items while you are here.

Go north of the exit to the Summit and you will fight a Galactic Grunt. Go down the climbable wall and continue east then go up the stairs to the right. Right next to the stairs in the wall next to a breakable rock is a hidden Max Ether. Go west and up the next stairs then go east to the rock which has a Big Mushroom on it. Go back down both stairs and go north to find the next Galactic Grunt. Continue north to fight another Galactic Grunt. Continue west and in the wall behind a breakable rock before the stairs is a hidden Full Restore. Go down both stairs to the south and in the wall next to the second stairs is a hidden Nugget. Continue south and go down the climbable wall and up the stairs to the south follow the path until you see a big rock. On the small rock north of this big rock is a hidden Rare Candy. On the rock on the ledge southeast of the Rare Candy is a hidden Revive. That's it for 1F 2 for now so head back to the Summit.

Trainers[edit]

Diamond and Pearl
Trainer Pokemon
Galactic Grunt
Galactic Grunt
Reward: Pokebuck.png1600
  • Golbat Golbat Lv. 40
Galactic Grunt
Galactic Grunt
Reward: Pokebuck.png1520
  • Wurmple Wurmple Lv. 34
  • Silcoon Silcoon Lv. 36
  • Beautifly Beautifly Lv. 38
Galactic Grunt
Galactic Grunt
Reward: Pokebuck.png1520
  • Croagunk Croagunk Lv. 35
  • Stunky Stunky Lv. 38
  • Croagunk Croagunk Lv. 38

Pokémon found[edit]

Diamond and Pearl
Pokémon Level Rate
Clefairy Clefairy 38-40 15%
Golbat Golbat 39 10%
Machoke Machoke 40 10%
Graveler Graveler 39,40 40%
Medicham Medicham 40 10%
Chingling Chingling 38,40 10%
Bronzong Bronzong 39,40 5%

Items[edit]

  • Max Ether (hidden) - southeast corner in the wall behind a breakable rock
  • Big Mushroom (hidden) - northwest of the Max Ether on a rock
  • Full Restore (hidden) - northwest corner in the wall behind a breakable rock
  • Nugget (hidden) - southeast of Full Restore in the wall after the two steps
  • Rare Candy (hidden) - south of entrance to Upper 1F 1 on a rock directly north of the big rock
  • Revive (hidden) - on a rock on the ledge southeast of the Rare Candy

One last time on the Summit[edit]

Here you your last rodeo on the Summit and now you will be heading to the entrance to resume climbing the mountain.

North of the entrance to 1F, you will climb a wall to go west. Continue west then go down the stairs and then go down both stairs to your left and go up the stairs after them. Next to the last stairs on a rock is a hidden TinyMushroom. To the west you will see the cave entrance to 4F 3 and more stairs. Go down the stairs and down the stairs after that then go all the way east to find a rock with a hidden Big Mushroom on it. Head back to the entrance to 4F 3 and go through it.

Pokémon found[edit]

The Pokémon are still the same as your visit visit to the Summit. Look at the table in that section.

Items[edit]

  • TinyMushroom (hidden) - on a rock east of entrance to 4F 3
  • Big Mushroom (hidden) - on a rock on the northernmost ledge in the northeast corner

4F 3[edit]

4F 3
4F 3

This floor is relatively small and straight foward compared to the other floors. It only has one hidden TinyMushroom on the second rock and wild Pokémon. Just follow the path to get to the stairs to 5F.

Pokémon found[edit]

Diamond and Pearl
Pokémon Level Rate
Clefairy Clefairy 38-40 15%
Golbat Golbat 39 10%
Machoke Machoke 39 10%
Graveler Graveler 38 20%
Medicham Medicham 39 10%
Chimecho Chimecho 40 5%
Chingling Chingling 40 5%
Bronzong Bronzong 38-40 25%

Items[edit]

  • TinyMushroom (hidden) - on second rock

5F[edit]

5F
5F

Follow the path south and battle the Galactic Grunt. On the rock just south of the first Galactic Grunt is a hidden Max Potion. Go up the stairs and continue following the path and on the southernmost rock is a hidden Stardust. Battle the Galactic Grunt as well. Head west and up the stairs to 6F.

Trainers[edit]

Diamond and Pearl
Trainer Pokemon
Galactic Grunt
Galactic Grunt
Reward: Pokebuck.png1520
  • Bronzor Bronzor Lv. 38
  • Glameow Glameow Lv. 38
Galactic Grunt
Galactic Grunt
Reward: Pokebuck.png1480
  • Bronzor Bronzor Lv. 37
  • Golbat Golbat Lv. 37

Pokémon found[edit]

Diamond and Pearl
Pokémon Level Rate
Clefairy Clefairy 40-42 15%
Golbat Golbat 41 10%
Machoke Machoke 41 10%
Graveler Graveler 40 20%
Medicham Medicham 41 10%
Chimecho Chimecho 41,42 10%
Bronzong Bronzong 40-42 25%

Items[edit]

  • Max Potion (hidden) - on rock just south of first Galactic Grunt
  • Stardust (hidden) - on the southernmost rock

6F[edit]

6F
6F

This is the final floor before you reach Spear Pillar! This was quite the climb and adventure and it's appropriate that this floor only has one Galactic Grunt in it to battle. Just follow the path and she will be in your way. After her then head north and go through the entrance to Spear Pillar.

Trainers[edit]

Diamond and Pearl
Trainer Pokemon
Galactic Grunt
Galactic Grunt
Reward: Pokebuck.png1520
  • Golbat Golbat Lv. 37
  • Glameow Glameow Lv. 37
  • Bronzor Bronzor Lv. 37

Pokémon found[edit]

Diamond and Pearl
Pokémon Level Rate
Clefairy Clefairy 40-42 15%
Golbat Golbat 41 10%
Machoke Machoke 41 10%
Graveler Graveler 40 20%
Medicham Medicham 41 10%
Chimecho Chimecho 41,42 10%
Bronzong Bronzong 40-42 25%

Spear Pillar[edit]

Spear Pillar
DiamondPearlPlatinum
Spear Pillar
Spear Pillar
Spear Pillar

There is no time to rest after your long journey here. You need to stop Team Galactic with their evil plan to destroy the world!

Go north and try to pass the two Galactic Grunts whom will stop you as they say something big is going to happen then they fight you in a double battle. Once you defeat them then heal your Pokémon and save since several events are going to happen.

Trainers[edit]

Diamond and Pearl
Trainer Pokemon
Galactic Grunt
Galactic Grunt
Reward: Pokebuck.png3040
Double battle
w/below Grunt
  • Stunky Stunky Lv. 38
  • Glameow Glameow Lv. 38
Galactic Grunt
Galactic Grunt
Reward: Pokebuck.png3040
Double battle
w/above Grunt
  • Dustox Dustox Lv. 38
  • Croagunk Croagunk Lv. 38

Cyrus uses the Red Chain to pry open a portal to another dimension and summons Dialga (Diamond) or Palkia (Pearl) to use their power. Dialga or Palkia then starts using their power and starts to destroy the world. Cyrus then says that this world cant be molded into the world that he wants so he must destroy it to create a new one where he is the ruler/deity of it.

Before you move forward further, double check that you have the right order for your Pokémon as you will face Commanders Mars and Jupiter then Cyrus right after with no break in between

After the cutscenes go forward and Mars a will challenge you to get her revenge and then Jupiter says she will be next. Barry shows up and says to not start the party without him so the battle becomes a Multi Battle with Barry versus the two commanders.

Barry now has a full team of 6 Pokémon. He starts out with Munchlax who knows Screech and Body Slam which is actually a good combo. Barry's starter Pokémon is also fully evolved finally.

Both commanders have Bronzor which can easily be beaten by Fire Type moves or if you want your beginning Pokémon to stay in line with Cyrus' battle then use a Luxray that knows Crunch (one of the best Dark Type moves). They also both have Golbat which you can beat with an Ice Type Pokémon that knows Blizzard, can hit both Golbats in the same attack phase. Their last Pokémon can be a little tricky and it depends on what Pokémon Barry sends out next. If he sends out Staraptor then send out a Ground type that knows Earthquake to kill the Skuntank first. If he sends out any other Pokémon then send out a Fighting Type to take out Purugly first.

Commander battles[edit]

Diamond and Pearl
Trainer Pokemon
Commander Mars
Commander Mars
Reward: Pokebuck.png7280
Multi battle
w/Jupiter
  • Bronzor Bronzor Lv. 41
  • Golbat Golbat Lv. 42
  • Purugly Purugly Lv. 45
Commander Jupiter
Commander Jupiter
Reward: Pokebuck.png7280
Multi battle
w/Mars
  • Bronzor Bronzor Lv. 41
  • Golbat Golbat Lv. 41
  • Skuntank Skuntank Lv. 46

After you beat them, Barry will heal your Pokémon and say that its your show now.

Dialga/Palkia starts to create a new galaxy but Uxie, Mesprit, and Azelf come and stop it, breaking the Red Chain in the process. Cyrus says be will capture the Lake Guardians again to make a new Red Chain then tries to take his vengeance out on you by battling you.

Galactic Boss Cyrus battle[edit]

Diamond and Pearl
Trainer Pokemon
Galactic Boss Cyrus
Galactic Boss Cyrus
Reward: Pokebuck.png8640
  • Honchkrow Honchkrow Lv. 45
  • Staryu Staryu Lv. 45
  • Crobat Crobat Lv. 46
  • Weavile Weavile Lv. 48

After you beat Cyrus he questions what your ultimate is and says that he is not giving up and he will come back. Aftet that Lucas/Dawn and Professor Rowan come and Rowan tells you that he doesn't know if Dialga/Palkia is mad or upset but its waiting to challenge you. Lucas/Dawn says that he ran into Barry who said he entrusted you to help the Legendary Pokémon and Lucas now entrusts you as well. Save, heal your Pokémon and get in a battle with Dialga or Palkia.

Legendary Pokémon battle[edit]

Don't waste your Master Ball on catching Dialga/Palkia as they have a high catch rate!

Pokemon 483Dialga.png

Dialga is a level 47 Steel/Dragon type Pokémon that knows Metal Claw, AncientPower, Dragon Claw and Roar of Time. Roar of Time is the Hyper Beam of Dragon type moves as Dialga needs a turn to recharge after it and its very powerful. AncientPower has the chance to increase all of Dialga's stats. Due to Dialga being part Dragon its resistant to elemental types such as Fire, Water, Electric, and Grass and since its also part Steel, its resistant to Ice as well which makes Dialga weak to Fighting, Ground, and Dragon type moves only.

First cause paralysis or sleep, then get its HP low and use False Swipe to get it to 1 HP. Throw Ultra Balls or Dusk Balls if battling at night until you catch Dialga.


Pokemon 484Palkia.png

Palkia is a level 47 Water/Dragon type Pokémon that knows Water Pulse, AncientPower, Dragon Claw and Spacial Rend. Water Pulse has a chance to confuse your Pokémon. AncientPower has a chance to increase all of Palkia's stats. Spacial Rend has high chance to crit hit you. Palkia is only weak to Dragon type moves since its resistant to Electric, Water, Fire, Grass and Ice.

First cause paralysis or sleep, then get its HP low and use False Swipe to get it to 1 HP. Throw Ultra/Net Balls or Dusk Balls if battling at night until you catch Palkia.

After you catch/defeat Dialga/Palkia go past where it stood to get an item that increases the power of your legendary's moves. You can leave via an Escape Rope or going through 1F 2. If you go through 1F 2 and reach 1F 1 then there is a hidden Hyper Potion on a rock and TM02 Dragon Claw

Items[edit]

  • Adamant Orb (Diamond only) - in the back
  • Lustrous Orb (Pearl only) - in the back

Celestic Town[edit]

Go to speak to Cynthia's Grandmother who will tell you a story about the other games Legendary Pokémon. This story will mark it as seen in your Pokédex which is needed for obtaining the National Dex later on.

Team Galactic remnants[edit]

Head to Team Galactics HQ in Veilstone City and you will out that Commander Saturn was left in charge of the team's operations. He decides that extremism is never the solution and Cyrus fooled everyone about it. Team Galactic isn't a threat anymore after this.

Catching the Lake Guardians[edit]

You can now catch the 3 Lake Guardians at the their respective lakes.

All of them are lvl 50 pure Psychic types so using a Dark, Ghost or Bug type Pokémon will do you wonders in these fights. You can use Dusk Balls for Uzue and Azelf as they are in caves and you can use Ultra Balls for Mesprit as it is out in the open.

Mesprit[edit]

Mesprit in Verity Cavern
Mesprit in Verity Cavern

Mesprit can be found in the Verity Cavern which is in the middle of Lake Verity. Once you interact with it, it will roam off and be a roaming Pokémon. You can use the Marking Map Pokétch app to find Mesprit but beware that if you fly to its location it will move elsewhere. The best place to catch it is on Route 205 and Valley Windworks as you can enter and exit both of these spots fairly easy.

It's also best to catch Mesprit now as there will be another roaming Pokémon later on in the game.

Uxie[edit]

Uxie in Acuity Cavern
Uxie in Acuity Cavern

Uxie can be found in Acuity Cavern which is in the middle of Lake Acuity. When you interact with it, you will battle it. Paralyze it or make it go to sleep then get it to red HP then start throwing Dusk Balls to capture it.

Azelf[edit]

Azelf in Valor Cavern
Azelf in Valor Cavern

Azelf can be found in Valor Cavern which is in the middle of Lake Valor. When you interact with it, you will battle it. Paralyze it or make it go to sleep then get it to red HP then start throwing Dusk Balls to capture it.

After you catch Azelf head to the east side of Hotel Grand Lake to see that you can finally go on Route 222 to get to Sunnyshore City.